発表論文

Solid-state Dynamics of Binuclear N-Heterocyclic Carbene Au(I) Rotor with para-Phenylene Rotator

Jiang, P.; Mikherdov, A. S.; Ito, H.*; Jin, M.* Chem. Lett. 2024, 53, upae139.
DOI: doi.org/10.1093/chemle/upae139

Crystallization-Induced Chirality Transfer in Conformationally Flexible Azahelicene Au(I) Complexes with Circularly Polarized Luminescence Activation

Jiang, P.; Mikherdov, A.S.; Ito, H.*; Jin, M.* J. Am. Chem. Soc. 2024, 146, 12463–12472.
DOI: 10.1021/jacs.4c00345

Pitched π-Stacking Crystal Structure and Two-Dimensional Electronic Structure of Acenaphtho[1,2-k]fluoranthene Analogues with Various Substituents

Yuki, T.; Yokokura, S.*; Jin, M.; Waizumi, H.; Nagahama, T.; Shimada, T.: Crystal Growth & Design 2024, 24, 1849–1856.
DOI: 10.1021/acs.cgd.3c01510

A Steric-Repulsion-Driven Clutch Stack of Triaryltriazines: Correlated Molecular Rotations and a Thermo-Responsive Gear-shift in the Crystalline Solid

Jin, M.*; Kitsu, R.; Hammyo, N.; Sato-Tomita, A.; Mizuno, M.; Mikherdov, A.; Tsitsvero, M.; Lyalin, A.; Taketsugu, T.; Ito, H.* J. Am. Chem. Soc. 2023, 145, 27512–27520.
DOI: 10.1021/jacs.3c08909

Single Crystal Growth of Cyclopenta-Fused Polycyclic Aromatic Hydrocarbon by the Naphthalene Flux Method: 2D Ambipolar Charge Transport Properties and NIR Absorption

Tanoguchi, H.; Yuki, T.; Yokokura, S.*; Yanase, T.; Jin, M.; Ito. H.; Nagahama, T.; Shimada, .T* ACS Appl. Electron. Mater. 2023, 5, 6266–6274.
DOI: 10.1021/acsaelm.3c01148

Giant Crystalline Molecular Rotors that Operate in the Solid State

Ando, R.; Sato-Tomita, A.; Ito, H.*; Jin, M.* Angew. Chem. Int. Ed. 2023, 135, e202309694.
DOI: 10.1002/ange.202309694

Solid-state mechanochemical cross-coupling of insoluble substrates into insoluble products by removable solubilizing silyl groups: Uniform synthesis of nonsubstituted linear oligothiophenes

Kubota, K.*; Kondo, K.; Seo, T.; Jin, M.; Ito, H.* RSC Adv. 2023, 13, 28652–28657.
DOI: 10.1039/D3RA05571J

Construction of a Helical Structure with a Parallel Alignment of Molecular Dipoles in Crystals by Utilizing a Halogen-3 Synthon and a Bulky Silyl Spacer

Hammyo, N. ; Jin, M.*; Ito, H.* Cryst. Growth Des. 2023, 23, 4514–4521.
DOI: 10.1021/acs.cgd.3c00282

Exploring Au(I) Involving Halogen Bonding with N-Heterocyclic Carbene Au(I) Aryl Complexes in Crystalline Media

Mikherdov, A. S.; Jin, M.*; Ito, H.* Chem. Sci. 2023, 14, 4485–4494.
DOI: 10.1039/D3SC00373F

In Situ and Real-Time Visualization of Mechanochemical Damage in Double-Network Hydrogels by Prefluorescent Probe via Oxygen-Relayed Radical Trapping

Zheng, Y.; Jiang, J.; Jin, M.*; Miura, D.; Lu, F. X.; Kubota, K.; Nakajima, T.; Maeda, S.*; Ito, H.*; Gong, J. P.* J. Am. Chem. Soc. 2023, 145, 7376–7389.
DOI: 10.1021/jacs.2c13764

Multidynamic Crystalline Molecular Rotors Comprising an N-Heterocyclic Carbene Binuclear Au(I) Complex Bearing Multiple Rotators

Jin, M.*; Matsuura, S.; Yamamoto, H.; Mizuno, M.; Ito, H.* Eur. J. Org. Chem. 2023, 26, e202201468.
DOI: 10.1002/ejoc.202201468

Distinct Fold-Mode Formation of Crystalline Cu(I) Helical Coordination Polymers with Alternation of the Solid-State Emission Using Shape of the Counter Anions

Jin, M.*; Ando, R.; Ito, H.* Inorg. Chem. 2022, 61, 3–9.
DOI: 10.1021/acs.inorgchem.1c02725

Single Crystal Growth of π-Conjugated Large Molecules without Solubilizing Alkyl Chains via Naphthalene Flux Method

Yanase, T.; Tanoguchi, H.; Sakai, N.; Jin, M.; Yamane, I.; Kato, M.; Ito, H.; Nagahama, T.; Shimada, T. Cryst. Growth. Des. 2021, 21, 4683–4689.
DOI: https://doi.org/10.1021/acs.cgd.1c00538

Charge-Transfer Crystal with Segregated Packing Structure Constructed with Hexaarylbenzene and Tetracyanoquinodimethane

Ando, R.; Jin, M.*; Ito, H.* CrystEngComm. 2021, 23, 5564–5568.
DOI: 10.1039/D1CE00726B

Introduction of a Luminophore into Generic Polymers via Mechanoradical Coupling with a Prefluorescent Reagent

Kubota, K.*; Toyoshima, N.; Miura, D.; Jiang, J.; Maeda, S.; Jin, M.*; Ito, H.* Angew. Chem. Int. Ed. 2021, 60, 16003–16008.
DOI: 10.1002/anie.202105381

Encapsulating N-Heterocyclic Carbene Binuclear Transition-Metal Complexes as a New Platform for Molecular Rotation in Crystalline Solid-State

Jin, M.*; Ando, R.; Jellen, M. J.; Garcia-Garibay, M. A.; Ito, H.* J. Am. Chem. Soc. 2021, 143, 1144–1153.
DOI: https://doi.org/10.1021/jacs.0c11981

Enhanced Gearing Fidelity Achieved Through Macrocyclization of a Solvated Molecular Spur Gear

Jellen, M.; Liepuoniute, I.; Jin, M.; Jones, C.; Yang, S.; Jiang, X.; Nelson, H.*; Houk, K.*; Garcia-Garibay, M.A.* J. Am. Chem. Soc. 2021, 143, 7740–7747.
DOI: https://doi.org/10.1021/jacs.1c01885

Anisotropic Thermal Expansion as the Source of Macroscopic and Molecular Scale Motion in Phosphorescent Amphidynamic Crystals

Jin, M.; Yamamoto, S.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.* Angew. Chem. Int. Ed. 2019, 58, 18003–18010.
DOI: 10.1002/anie.201909048

Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color

Jin, M.; Sumitani, T.; Sato, H.; Seki, T.*; Ito, H.* J. Am. Chem. Soc. 2018, 140, 2875–2879.
DOI: 10.1021/jacs.7b12455

Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of 1,4-bis[tri-(p-fluorophenyl)phosphane-gold(I)-ethynyl]benzene

Jin, M.; Chung, T. J.; Seki, T.; Ito, H.*; Garcia-Garibay, M. A.* J. Am. Chem. Soc. 2017, 139, 18115–18121.
DOI: 10.1021/jacs.7b11316

Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups

Jin, M.; Seki, T.*; Ito, H.* J. Am. Chem. Soc. 2017, 139, 7452–7455.
DOI: 10.1021/jacs.7b04073

Copper(I)-Catalyzed Enantioselective Nucleophilic Borylation of Ketones: Synthesis of Enantioenriched Chiral Tertiary alpha-Hydroxyboronates

Kubota, K.; Osaki, S. ; Jin, M.; Ito, H.* Angew. Chem. Int. Ed. 2017, 56, 6646–6650.
DOI: 10.1002/anie.201702826

Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I) Isocyanide Complex with Mechanical Reactivation

Seki, T.*; Jin, M.; Ito, H.* Inorg. Chem. 2016, 55, 12309–12320.
DOI: 10.1021/acs.inorgchem.6b02107

Luminescent mechanochromism of a chiral complex: Distinct crystal structure and color changes of racemic and homochiral gold(I) isocyanide complexes with a binaphthyl moiety

Jin, M.; Seki, T.*; Ito, H.* Chem. Commun. 2016, 52, 8083–8086.
DOI: 10.1039/C6CC03541H

Computational Insight into the Enantioselective Nucleophilic Borylation of a Polarized C=O Double Bond Catalyzed by Di-phosphine-Borylcopper(I) Complexes

Kubota, K.; Jin, M.; Ito, H.* Organometallics 2016, 35, 1376–1383.
DOI: 10.1021/acs.organomet.5b00621

Synthesis of water-soluble polyisocyanates with the oligo(ethylene glycol) side-chain as new thermoresponsive polymers

Sakai, N.; Jin, M.; Sato, S.; Satoh, T.; Kakuchi, T. Polym. Chem. 2014, 5, 1057–1062.
DOI: 10.1039/C3PY00972F